Kelp Farming and Ice Dyking

Aaron Franklin

Kelp farming and ice dyking for habitat enhancement 

and carbon-negative fuels and chemical production.

By Aaron Franklin

A purpose-built craft like this Ground effect plane / hovercraft triphibian concept could be ideal.

The laterally-rigid sideskirts with vertically-flexible surface-contouring ski bottoms would allow transitions between air, water, ice, snow, earth surfaces of all types and the waterscoop tail could directly hose the water onto the ice with foil effect to counter lateral reaction thrust. Snow making, firefighting, and ecology seeding also in its functionality.

At pumping of 10tons per second, 50m x 100m/s = 5000sqm, 10000kg/5000sqm = 2 kg per sqm per pass. About 2mm per pass.

If we assume conditions that will allow 2 mm to freeze in 30 seconds. then 4mm per minute = 240mm per hour = 5760mm (near 6m thick) per day could be made of 50m wide by 100m/s x 30s = 3km long of icedyke by a mobile spray vehicle at 100m/s.

3000m x 6m x 50m = 900 000 tons per day of ice making.

A fleet of 50 working for 100 days therefore could make 5000 x 900 000 = 45 000 000 000 tons or near 5 cubic kilometers of ice. 

If we are looking at an average needed to ground them of say 30m thick, then 50m wide is cross section area of 1500 sqm.

5 000 000 000 cubic m / 1500 sqm = 3.33333 million meters or 3333 km.

A ball park figure of 1000kw vehicle power would seem adequate to do this.

Very likely a rope mesh reinforcement would need to be floated on the water and anchored in place to hold together the dyke that has been formed. Doing this work in polynyas seems the best way, then towing into position of sections to be anchored and further thickened.

If 100 such vehicles were used you've got near seven thousand km of icedyke which could be enough for such a layout as this:

Kelp farming, by Aaron Franklin, on background image by Shakhova et al., 2010. 

For methane plume hotspots to the surface, hexagonal tiles would need to be formed and towed into place, if they are too rich for ice to form inside the rings in situ.

Stationary pumping systems might have to high costs per area in most places with limits to small volumes per pump due to area feasible to distribute the water to and ice layup rates. Though in saying this, high cost is often seen as a benefit for commercial interests. They can make more money doing it the hard way.

The purposes of kelp farming in the less methane emissive areas is as follows:

• Biomass for biofuels and biochemicals of around 500 ton per hectare per year can be harvested.
• The growing kelp oxygenates the water to support consumption of methane and river in-flux of organic carbon.
• The artificial kelp forests provide habitat and food for a diverse and rich ecology with fisheries and abalone/ mussel/ crabs / lobster etc farming potential
• Unlike micro algae, the kelp biomass is easily harvested, so it would not rot and cause oxygen depletion of the water at the end of summer.
• Sedimentation rates and water clarity are vastly improved by the kelp forests, thereby improving albedo and enhancing natural carbon burial in sediments.
• Simple and low cost infrastructure only is neccessary to process the kelp locally into liquids for low transport costs to refineries for further upgrading.
• It would be easy to use the CO2 from an initial biomass pyrolysis to convert methane collected nearby to methanol for easy low cost transportation.

Combining these systems would allow zero carbon emission liquid fuels via the energy component of the fossil methane and biomass being used as hydrogen and the carbon turned into biochar and high performance bioglues and recyclable polymers, allowing further long-term carbon sequestration by wood, biofibre, etc., and component for construction materials, also replacing high carbon-emission steel, concrete etc.

Methane-Eating Microbes Need Trace Metal

Methane can be released from hydrates during an earthquake or by rising ocean temperatures, and this can contribute significantly to global warming. Stimulating microbes to consume the methane in the water could prevent methane from entering the atmosphere and, as a new study has found, trace metals may hold the key. The following is from a Georgia Institute of Technology news release. 

A pair of cooperating microbes on the ocean floor “eats” this methane in a unique way, and a new study provides insights into their surprising nutritional requirements. Learning how these methane-munching organisms make a living in these extreme environments could provide clues about how the deep-sea environment might change in a warming world.

Scientists already understood some details about the basic biochemistry of how these two organisms consume methane, but the details of the process have remained mysterious. The new study revealed that a rare trace metal – tungsten, also used as filaments in light bulbs — could be important in the breakdown of methane.

Glass works in a chamber where she can control the oxygen
levels to mimic the deep sea environment. Credit: Rob Felt.

“This is the first evidence for a microbial tungsten enzyme in low temperature ecosystems,” said Jennifer Glass, an assistant professor in the School of Earth and Atmospheric Sciences at the Georgia Institute of Technology.

The study was recently published online in the journal Environmental Microbiology. The research was sponsored by the Department of Energy, NASA Astrobiology Institute and the National Science Foundation. Glass conducted the research while working as a NASA Astrobiology post-doctoral fellow at the California Institute of Technology, in the laboratory of professor Victoria Orphan.

The methane-eating organisms, which live in symbiosis, consume methane and excrete carbon dioxide.

“Essentially, they are eating it,” Glass said. “They are using some of the methane as a carbon source and most of it as an energy source.”

Phylogenetically speaking, one microbial partner belongs to the Bacteria, and the other is in the Archaea, representing two distinct domains of life. The archaea is named ANME, or anaerobic methanotrophic archaea, and the other is a sulfate-utilizing deltaproteobacteria. Together, the organisms form “beautiful bundles,” Glass said.

For a close-up view of the action on the sea floor, the research team used the underwater submersible robot Jason. The robot is an unmanned, remotely operated vehicle (ROV) and can stay underwater for days at a time. The research expedition in which Glass participated was Jason’s longest continuous underwater trip to date, at four consecutive days underwater.

The carbon dioxide excreted by the microbes reacts with minerals in the water to form calcium carbonate. As the researchers saw through Jason’s cameras, calcium carbonate has formed an exotic landscape on the ocean floor over hundreds of years.

“There are giant mountains on the seafloor of calcium carbonate,” Glass said. “They are gorgeous. It looks like a mountain landscape down there.”

While on the seafloor, Jason’s robotic arm collected samples of sediment. Back in the lab, researchers sequenced the genes and proteins in these samples. The collection of genes constitutes the meta-genome of the sediment, or the genes present in a particular environment, and likewise the proteins constitute a metaproteome. The research team discovered evidence that an enzyme used by microbes to “eat” methane may need tungsten to operate.

The enzyme (formylmethanofuran dehydrogenase) is the last in the pathway of converting methane to carbon dioxide, an essential step for methane oxidation.

Microorganisms in low temperature environments typically use molybdenum, which has similar chemical properties to tungsten but is usually much more available (tungsten is directly below molybdenum on the periodic table). Why these archaea appear to use tungsten is unknown. One guess is that tungsten may be in a form that is easier for the organisms to use in methane seeps, but that question will have to be answered in future experiments.

References

Methane-Munching Microorganisms Meddle with Metals - Research News, Georgia Institute of Technology
http://www.news.gatech.edu/2013/11/11/methane-munching-microorganisms-meddle-metals

Geochemical, metagenomic and metaproteomic insights into trace metal utilization by methane-oxidizing microbial consortia in sulphidic marine sediments, Jennifer B. Glass et al. (2013)
http://onlinelibrary.wiley.com/doi/10.1111/1462-2920.12314/abstract

Supersonic and high velocity Subsonic Saltwater and Freshwater Cloud Making Cannons

Aaron Franklin

By Aaron Franklin

As a compliment to cloud brightening systems, these for use in calm blue sky conditions, or windy blue sky conditions, over Ocean, sea and glacial ice, and land permafrost.

Also may be very important this year for as high tech cloud brightening/making doesn't look like it will be easy to get out in large unit numbers, while there is existing firepump systems that are available in numbers we need now.

Also are essentially no different from snowmaking gear used on ski fields, except for making snow, lower velocity is fine, and no CCN's are required. Just air below 0C, and freshwater.

- High pressure / high volume fire-fighting/water cannon pump gear can be used as is, or modified for higher pressure and kW capacities to increase output volumes at similar nozzle velocities.

An aerated system looks best at this point because:

• By using de Laval nozzles ( convergent-divergent, supersonic and tight stream output ) the aerated water can be accelerated by expansion to high velocity or Supersonic speed as it leaves the divergent exit section of the nozzle.
  
• Nozzle friction is reduced because air sticks to the surface and creates a gaseous boundary layer.
  
• For Aeration, copper or soft stainless tubes CNC laser perforated, swaged to flare to hexagonal ends, stacked for a honeycomb aeration section (just like a ww2 spitfire radiator except they had the water on the outside of the tubes and no holes) fed with compressed air, in the water feed before the pumps can entrain microbubbles in the water. 

• Alternatively supersonic streams can be achieved with unaerated water with convergent nozzles, but more pressure is required.
  
• The high kinetic energy of the water stream will cause excellent dispersion, and evaporation, via transonic shockwaves as the stream slows, shedding its outer layer as it goes, eventually disintegrating completely either below the altitude where enough kinetic energy, has converted to gravitational potential energy for the stream to go transonic if the stream is below a critical diameter, or not far above that altitude if its above that diameter.
  
• If its a high velocity Subsonic jet it will still shatter the droplets and evaporate lots of, if not all of them by air turbulence and high differential speed energy conduction/friction evaporation.
  
• We need to look at freshwater versions as well. This because saltwater rain will be fine over open oceans but it landing on ice and land permafrost will make them melt faster. And saltwater rain on land living ecologies is not at all good either. There's going to be a big use for them to protect the land permafrosts with cloud cover too. Freshwater versions will benefit from using water with diatoms growing in it, as these act as cloud droplet condensation nuclei, just like salt crystals.
  
  Seeding tundra lakes with diatoms will also eat CO2, oxygenate the water enhancing aerobic digestion of dissolved methane and other organic carbon. Removing the diatoms with the water for cloud cannons will also remove excess nutrients from the waters, provide aeration for skyborne digestion of DOC to CO2, and will clean up lakes to make them better for winter snow-making watersources.
  
• We're going to need to straffe the sky with these things for best cloudmaking effect, so we need to get ready to mount them on naval gun turrets with computer controlled tracking systems and look into parking tanks and APC's with suitable turrets on container ship decks.
  
  Using these tanks and APC's, maybe fixed installations when the wind is blowing, with cloud-cannons on the arctic tundras can help protect the permafrosts. 

Calculations and conclusions, for peer review:

These are based on a sonic speed case. Faster will give more range but less volume and slower more volume but less range, for a given pump system.

speed of sound 330m/s

Ep= mgh

Ek= 0.5mv^2

Ek sonic (1 kg water)= 0.5 x 1 x 330^2 = 54450J

54450=mgh=1 x 9.8m/s^2 x h

vertical ballistic altitude h=54450/9.8 = 5.556km


cloud water content = 0.3g/m^3

10m thickness= 3g/m^2

100m thickness= 30g/m^2

4 sqkm= 4,000,000 m^2


Fixed position still air straffing:

A=pi.r^2

r=sqrt(A/pi)


4 sqkm horizontal Cannon range r = sqrt(4/pi)= 1.12km


Moving ship, land tanker, or wind blowing fixed position straffing:

14m/s = 50km/hr (vehicle or wind velocity)

-4 sqkm per hr requires only 4/50= 80m watercannon range.


Water volume and flow rates:

4sqkm at 10m thick= 12000 liters= 12 tons (less than 10min with flow rates of existing fire pumps)

at 100m thick = 120 tons (could be less than an hour per firepump)

1 small Supersonic cloud cannon could produce 24hr x 4sqkm/hr = 96sqkm of 100m thick cloud per day.


Kinetic energy:

120,000 liters per hr / 3600 = 33.3 L/s

12,000 liters per hr / 3600 = 3.3 L/s

Ek Sonic 1kg = 54.45 kJ


kW 100m thick, 4sqkm cloud layer in an hr = 33.3 L/s x 54.45kJ = 1813 kW

- existing pump designs would need to be upgraded for higher power/pressure to produce this much cloud, if supersonic velocities are required, but this is a very small engineering challenge. Ships trawler size and up, and tanks have more than enough kWs for the job. Rapid small amplitude vertical oscillation of the jet release angle should lay down the average 100m thick cloud bank aimed for.

kW 10m thick, 4sqkm cloud layer in an hr = 3.3 L/s x 54.45kJ = 181.3 kW

- this looks good for mobile straffing with existing fire pumps, provided aerated water and deLavel nozzles are used to produce supersonic velocities. The range required for 4 sqkm per hr coverage at only 80m is no problem for the small volume, aerated supersonic water flows possible from existing fire pumps.


Latent heat of evaporation and Ek sonic considerations:

latent heat of evaporation water = 2260 kJ per L

Ek sonic water = 54.45 kJ per L

• If the very small water droplets produced by transonic shockwaves shattering any water breaking from the decaying jet should partially or fully evaporate (this will depend on stream velocity) they will be doing this by absorbing a lot of heat from the air they are landing in. This will cool and supersaturate the air with water vapour, and result in rapid droplet condensation in both saltwater and freshwater versions proposed.
  
• I am advised that we can expect around 60% humidity levels in arctic conditions. As the evaporative cooling effect will cool the air that the stream droplets land in, and vast quantities of very small cloud nucleation salt crystals will be formed, we can expect a lot more cloud to be formed than the above examples suggest.
  
• Aeration should result in more and smaller salt crystals, and droplets. In part due to microbubbles enhancing droplet fragmentation. Also due to supersaturation of the water with air, enhanced by evaporation. This causing many disturbances per drop as new bubbles precipitate, and initiate many salt crystals per droplet to precipitate. Turbulence will also initiate precipitation of air and salt crystals in the supersaturated droplet.
  
• How much extra cloud will depend on how much atmosperic turbulence and mixing is generated by the straffing pattern, and on local temperature and humidity conditions.
  
• Less mixing will also result in larger cloud droplets.
  
• Too much mixing will run the risk of forming little cloud at all, as the humidity levels may be too low to form any droplets at all around the salt crystals.
  
• It's quite likely that 500-600kph will be sufficient velocity. This would produce about 15 litres per second from standard firepump gear. A good estimate seems to be that this would initially produce around 100sqkm of 100m thick cloud bank per day. However from what I am hearing there is likely to be a repeating cycle of droplet evaporation - re nucleation of new droplets - back to droplet evaporation, due to the added water vapour and downwind cooling effects. So total cloud produced may be more than this.
  
• We should start testing on these ASAP. Others doing testing too, would be a good thing.

Funding of Carbon Air Capture

Air capture of carbon dioxide is an essential part of the blueprint to reduce carbon dioxide to acceptable levels. Fees on conventional jet fuel seem the most appropriate way to raise funding to help with the development of air capture technology. Why target jet fuel? In most other industries, there are ready alternatives to the use of fossil fuel. Electricity can be produced by wind turbines or by solar or geothermal facilities with little or no emissions of greenhouse gases. In the case of aviation, though, the best we can aim for, in the near future at least, is biofuel. Technically, there seem to be no problems in powering aircraft with biofuel. Back in Jan 7, 2009, a Continental Airlines commercial aircraft (a Boeing 737-800) was powered in part by algae oil, supplied by Sapphire Energy. The main hurdle appears to be that algae oil is not perceived as price-competitive with fossil fuel-based jet fuel. Additionally, the aviation industry can offset emissions, e.g. by funding air capture of carbon dioxide. The carbon dioxide thus captured could be partly used to produce fuel, which could in turn be used by the aviation industry, as pictured on the left. The carbon dioxide could also be used to assist growth of biofuel, e.g. in greenhouses. Algae can grow 20 to 30 times faster than food crops. A CNN report, more than a year ago, mentions Vertigro's claim to be able to grow 100,000 gallons of algae oil per acre per year by growing algae in clear plastic bags suspended vertically in a greenhouse. Given the right temperature and sufficient supply of light, water and nutrients, algae seem able to supply an almost limitless amount of biofuel. The potential of algae has been known for decades. As another CNN report describes, the U.S. Department of Energy (DoE) had a program for nearly two decades, to study the potential of algae as a renewable fuel. The program was run by the DoE's National Renewable Energy Laboratory (NREL) and was terminated by 1996. At that time, a NREL report concluded that an area around the size of the U.S. state of Maryland could cultivate algae to produce enough biofuel to satisfy the entire transportation needs of the U.S. In conclusion, it would make sense to impose fees on conventional jet fuel and use the proceeds of those fees to fund air capture of carbon dioxide. Apart from growing algae in greenhouses, we should also consider growing them in bags. NASA scientists are proposing algae bags as a way to produce renewable energy that does not compete with agriculture for land or fresh water. It uses algae to produce biofuel from sewage, using nutrients from waste water that would otherwise be dumped and contribute to pollution and dead zones in the sea. The NASA article conservatively mentions that some types of algae can produce over 2,000 gallons of oil per acre per year. In fact, most of the oil we are now getting out of the ground comes from algae that lived millions of years ago. Algae still are the best source of oil we know. In the NASA proposal, there's no need for land, water, fertilizers and other nutrients. As the NASA article describes, the bags are made of inexpensive plastic. The infrastructure to pump sewage to the sea is already in place. Economically, the proposal looks sound, even before taking into account environmental benefits. Jonathan Trent, lead research scientist on the Spaceship Earth project at NASA Ames Research Center, Moffett Field, California, envisages large plastic bags floating on the ocean. The bags are filled with sewage on which the algae feed. The transparent bags collect sunlight that is used by the algae to produce oxygen by means of photosynthesis. The ocean water helps maintain the temperature inside the bags at acceptable levels, while the ocean's waves also keep the system mixed and active. The bags will be made of “forward-osmosis membranes”, i.e. semi-permeable membranes that allow fresh water to flow out into the ocean, while preventing salt from entering and diluting the fresh water inside the bag. Making the water run one way will retain the algae and nutrients inside the bags. Through osmosis, the bags will also absorb carbon dioxide from the air, while releasing oxygen. NASA is testing these membranes for recycling dirty water on future long-duration space missions. As the sewage is processed, the algae grow rich, fatty cells that are loaded with oil. The oil can be harvested and used, e.g., to power airplanes. In case a bag breaks, it won’t contaminate the local environment, i.e. leakage won't cause any worse pollution than when sewage is directly dumped into the ocean, as happens now. Exposed to salt, the fresh water algae will quickly die in the ocean. The bags are expected to last two years, and will be recycled afterwards. The plastic material may be used as plastic mulch, or possibly as a solid amendment in fields to retain moisture. A 2007 Bloomberg report estimated that the Gulf of Mexico's Dead Zone would reach more than half the size of Maryland that year and stretch into waters off Texas. The Dead Zone endangers a $2.6 billion-a-year fishing industry. The number of shrimp fishermen licensed in Louisiana has declined 40% since 2001. Meanwhile, U.S. farmers in the 2007 spring planted the most acreage with corn since 1944, due to demand for ethanol. As the report further describes, the Dead Zone is fueled by nitrogen and other nutrients pouring into the Gulf of Mexico, and corn in particular contributes to this as it uses more nitrogen-based fertilizer than crops such as soybeans. The Louisiana coast seems like a good place to start growing algae in bags floating in the sea, filled with sewage that would otherwise be dumped there. It does seem a much better way to produce biofuel than by subsidizing corn ethanol. According to zFacts.com, corn ethanol subsidies totaled $7.0 billion in 2006 for 4.9 billion gallons of ethanol. That's $1.45 per gallon of ethanol (or $2.21 per gallon of gas replaced). As zFacts.com explains, besides failing to help with greenhouse gases and having serious environmental problems, corn ethanol subsidies are very expensive, and the political backlash in the next few years, as production and subsidies double, will damage the effort to curb global warming. At UN climate talks in Bonn, the world's poorest nations proposed a levy of about $6 on every flight to help them adapt to climate change. Benito Müller, environment director of the Oxford Institute for Energy Studies and author of the proposal, said that air freight was deliberately not included. The levy could raise up to $10 billion per year and would increase the average price of an international long-haul fare by less than 1% for standard class passengers, but up to $62 for people traveling first class. In the light of those amounts, it doesn't seems unreasonable to expect that fees imposed on conventional jet fuel could raise billions per year. Proceeds could then be used to fund rebates on air capture of carbon dioxide, which could be pumped into the bags on location to enhance algae growth. Air capture devices could be powered by surplus energy from offshore wind turbines. With the help of such funding, the entire infrastructure could be set up quickly, helping the environment, creating job opportunities, making the US less dependent on oil imports, while leaving us with more land and water to grow food, resulting in lower food prices.